Information card for entry 4320289

Structure parameters

• Formula: C30 H41 N5 Si2 W
• Calculated formula: C30 H41 N5 Si2 W
• SMILES: [W]1(=Nc2ccccc2)(N([Si](C)(C)C)c2c(N1[Si](C)(C)C)cccc2)([n]1ccc(cc1)C)[n]1ccc(cc1)C
• Title of publication: Coordinatively Unsaturated W(IV)-Bis(pyridine) Complexes, a Reactive Source of W(IV)
• Authors of publication: R. C. Mills; S. Y. S. Wang; K. A. Abboud; J. M. Boncella
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 5077 - 5082
• a: 13.6142 ± 0.0007 Å
• b: 12.7895 ± 0.0006 Å
• c: 19.054 ± 0.001 Å
• α: 90°
• β: 101.72 ± 0.001°
• γ: 90°
• Cell volume: 3248.5 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0366
• Residual factor for significantly intense reflections: 0.0248
• Weighted residual factors for significantly intense reflections: 0.0563
• Weighted residual factors for all reflections included in the refinement: 0.0626
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No