Information card for entry 4320315

Structure parameters

• Formula: C18 H33 N2 O2 Rh S2
• Calculated formula: C18 H33 N2 O2 Rh S2
• SMILES: [Rh]1234(N(S(=O)C(C)(C)C)C(=N[S]1(=O)C(C)(C)C)C)[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Synthesis and Crystal Structure of a Unique and Homochiral N,S-Bonded N,N'-Bis(tert-butanesulfinyl)amidinate Rhodium(I) Complex
• Authors of publication: Andrew J. Souers; Timothy D. Owens; Allen G. Oliver; Frederick J. Hollander; Jonathan A. Ellman
• Journal of publication: Inorganic Chemistry
• Year of publication: 2001
• Journal volume: 40
• Pages of publication: 5299 - 5301
• a: 9.7213 ± 0.0001 Å
• b: 10.9246 ± 0.0002 Å
• c: 19.3747 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2057.62 ± 0.06 ų
• Cell temperature: 174.2 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for significantly intense reflections: 0.0195
• Weighted residual factors for all reflections included in the refinement: 0.0212
• Goodness-of-fit parameter for all reflections included in the refinement: 0.782
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No