Information card for entry 4321189

Structure parameters

• Formula: C61 H56 Ag Au6 B Cl2 F4 N12
• Calculated formula: C61 H56 Ag Au6 B Cl2 F4 N12
• Title of publication: Luminescent Chains Formed from Neutral, Triangular Gold Complexes Sandwiching TlI and AgI. Structures of {Ag([Au(μ-C2,N3-bzim)]3)2}BF4.CH2Cl2, {Tl([Au(μ-C2,N3-bzim)]3)2}PF6.0.5THF (bzim = 1-Benzylimidazolate), and {Tl([Au(μ-C(OEt)NC6H4CH3)]3)2}PF6.THF, with MAu6 (M = Ag+, Tl+) Cluster Cores
• Authors of publication: Alfredo Burini; Rita Bravi; John P. Fackler,; Rossana Galassi; Tiffany A. Grant; Mohammad A. Omary; Bianca R. Pietroni; Richard J. Staples
• Journal of publication: Inorganic Chemistry
• Year of publication: 2000
• Journal volume: 39
• Pages of publication: 3158 - 3165
• a: 14.4505 ± 0.0001 Å
• b: 15.098 ± 0.002 Å
• c: 15.9571 ± 0.0011 Å
• α: 106.189 ± 0.003°
• β: 103.551 ± 0.005°
• γ: 101.31 ± 0.005°
• Cell volume: 3120.3 ± 0.5 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0894
• Residual factor for significantly intense reflections: 0.0572
• Weighted residual factors for significantly intense reflections: 0.1004
• Weighted residual factors for all reflections included in the refinement: 0.1201
• Goodness-of-fit parameter for all reflections included in the refinement: 1.196
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No