Information card for entry 4321261

Structure parameters

• Common name: [Co(S~2~OS,S')(dmpp)~2~]PF~6~
• Chemical name: Bis{1,3-bis(dimethylphosphino)propane}{oxodisulfido(2-)-S,S'}cobalt(III) hexafluorophosphate
• Formula: C14 H36 Co F6 O P5 S2
• Calculated formula: C14 H36 Co F6 O P5 S2
• Title of publication: Oxidative Additions of cyclo-Octasulfur and cyclo-Octaselenium to the Cobalt(II) Complex of 1,3-Bis(dimethylphosphino)propane (dmpp): Crystal Structures and Spectroscopic Properties of [Co(S2O)(dmpp)2]PF6 and [Co(Se2)(dmpp)2]BF4
• Authors of publication: Takayoshi Suzuki; Naoki Tsuji; Kazuo Kashiwabara; Kazuyuki Tatsumi
• Journal of publication: Inorganic Chemistry
• Year of publication: 2000
• Journal volume: 39
• Pages of publication: 3938 - 3941
• a: 13.652 ± 0.005 Å
• b: 11.792 ± 0.003 Å
• c: 16.253 ± 0.003 Å
• α: 90°
• β: 98.05 ± 0.02°
• γ: 90°
• Cell volume: 2590.7 ± 1.3 ų
• Cell temperature: 296.2 K
• Ambient diffraction temperature: 296.2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0611
• Weighted residual factors for all reflections included in the refinement: 0.0628
• Goodness-of-fit parameter for all reflections included in the refinement: 1.97
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No