Information card for entry 4322110

Structure parameters

• Chemical name: cis-[{Cp(dppe)Fe-NC-}2Pt(bipy)](SbF6)2
• Formula: C74 H66 F12 Fe2 N4 P4 Pt Sb2
• Calculated formula: C74 H66 F12 Fe2 N4 P4 Pt Sb2
• SMILES: [Pt]1([n]2c(c3[n]1cccc3)cccc2)(C#[N][Fe]12345([P](c6ccccc6)(c6ccccc6)CC[P]1(c1ccccc1)c1ccccc1)[cH]1[cH]2[cH]3[cH]4[cH]51)C#[N][Fe]12345([P](c6ccccc6)(c6ccccc6)CC[P]1(c1ccccc1)c1ccccc1)[cH]1[cH]2[cH]3[cH]4[cH]51.[Sb](F)(F)(F)(F)(F)[F-].[Sb](F)(F)([F-])(F)(F)F
• Title of publication: Linear and Bent M(μ-CN)Pt(μ-CN)M Chains: Probes for Remote Metal-Metal Interactions
• Authors of publication: Guy N. Richardson; Udo Brand; Heinrich Vahrenkamp
• Journal of publication: Inorganic Chemistry
• Year of publication: 1999
• Journal volume: 38
• Pages of publication: 3070 - 3079
• a: 32.12 ± 0.006 Å
• b: 32.12 ± 0.006 Å
• c: 14.46 ± 0.003 Å
• α: 90°
• β: 90°
• γ: 120°
• Cell volume: 12920 ± 4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 8
• Space group number: 169
• Hermann-Mauguin space group symbol: P 61
• Hall space group symbol: P 61
• Residual factor for all reflections: 0.0989
• Residual factor for significantly intense reflections: 0.0635
• Weighted residual factors for significantly intense reflections: 0.1395
• Weighted residual factors for all reflections included in the refinement: 0.1575
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No