Information card for entry 4322629

Structure parameters

• Formula: C74 H114 B2 N4 O13 Os P4
• Calculated formula: C74 H114 B2 N4 O13 Os P4
• SMILES: [Os]([P](OCC)(OCC)OCC)([P](OCC)(OCC)OCC)([P](OCC)(OCC)OCC)([P](OCC)(OCC)OCC)([NH2]N)[NH2]N.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.[B-](c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1.CCO
• Title of publication: Mono- and Bis(hydrazine) Complexes of Osmium(II): Synthesis, Reactions, and X-ray Crystal Structure of the [Os(NH2NH2)2{P(OEt)3}4](BPh4)2 Derivative
• Authors of publication: Gabriele Albertin; Stefano Antoniutti; Alessia Bacchi; Massimo Bergamo; Emilio Bordignon; Giancarlo Pelizzi
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 479 - 489
• a: 20.55 ± 0.004 Å
• b: 19.663 ± 0.004 Å
• c: 20.843 ± 0.004 Å
• α: 90°
• β: 99.84 ± 0.09°
• γ: 90°
• Cell volume: 8298 ± 4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.3598
• Residual factor for significantly intense reflections: 0.0909
• Weighted residual factors for all reflections: 0.3906
• Weighted residual factors for significantly intense reflections: 0.2168
• Goodness-of-fit parameter for all reflections: 0.842
• Goodness-of-fit parameter for significantly intense reflections: 1.167
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No