Information card for entry 4322919

Structure parameters

• Chemical name: ..... bis((mu|4$-benziimidazole-2-thiolato-S,S,N,N')-(dicarbonyl-rhodium(i))- (mu!2$-chloride-(dicarbonyl-rhodium(i))-((eta$4!-1,5-cyclo-octadiene)- rhodium(i)))) 1.5 dichloromethane solvate
• Formula: C39.5 H35 Cl5 N4 O8 Rh6 S2
• Calculated formula: C40 H32 Cl5 N4 O8 Rh6 S2
• Title of publication: Hydrogen Bonding and Isomerism Arising from the Coordination Modes of Bridging Benzimidazole-2-thiolate Ligands in Tetranuclear Rhodium Complexes
• Authors of publication: Cristina Tejel; B. Eva Villarroya; Miguel A. Ciriano; Andrew J. Edwards; Fernando J. Lahoz; Luis A. Oro; Maurizio Lanfranchi; Antonio Tiripicchio; Marisa Tiripicchio-Camellini
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 3954 - 3963
• a: 16.967 ± 0.004 Å
• b: 14.289 ± 0.003 Å
• c: 11.872 ± 0.002 Å
• α: 71.9 ± 0.02°
• β: 68.24 ± 0.02°
• γ: 77.6 ± 0.02°
• Cell volume: 2524.7 ± 1 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 295 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0359
• Weighted residual factors for significantly intense reflections: 0.0474
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No