Information card for entry 4323005

Structure parameters

• Chemical name: bis(/m-2,6-bis(Diphenylphosphino)-pyridine-N,P)-tetrachloro-di-molybdenum (II), dichloromethane solvate
• Formula: C60 H50 Cl8 Mo2 N2 P4
• Calculated formula: C60 H50 Cl8 Mo2 N2 P4
• SMILES: c1ccccc1[P](c1cccc2[n]1[Mo]1(Cl)([P](c3[n](c(ccc3)[P](c3ccccc3)c3ccccc3)[Mo]1([P]2(c1ccccc1)c1ccccc1)(Cl)Cl)(c1ccccc1)c1ccccc1)Cl)c1ccccc1.C(Cl)Cl.C(Cl)Cl
• Title of publication: Ligand Exchange or Reduction at Multiply Bonded Dimetal Units of Molybdenum and Rhenium by 2,6-Bis(diphenylphosphino)pyridine
• Authors of publication: F. Albert Cotton; Evgeny V. Dikarev; Glenn T. Jordan; Carlos A. Murillo; Marina A. Petrukhina
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 4611 - 4616
• a: 15.475 ± 0.002 Å
• b: 11.5958 ± 0.0007 Å
• c: 16.7637 ± 0.0006 Å
• α: 90°
• β: 98.178 ± 0.005°
• γ: 90°
• Cell volume: 2977.6 ± 0.4 ų
• Cell temperature: 242 ± 2 K
• Ambient diffraction temperature: 242 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0807
• Residual factor for significantly intense reflections: 0.0518
• Weighted residual factors for all reflections: 0.1479
• Weighted residual factors for significantly intense reflections: 0.1341
• Goodness-of-fit parameter for all reflections: 1.092
• Goodness-of-fit parameter for significantly intense reflections: 1.213
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No