Information card for entry 4323157

Structure parameters

• Chemical name: trans-fluorooxo-bis(diphenylphosphinoethane)tungsten(IV)tetrafluoroborate.
• Formula: C52 H48 B F5 O P4 W
• Calculated formula: C52 H48 B F5 O P4 W
• Title of publication: Synthesis and Characterization of a Stable trans-Dioxo Tungsten(IV) Complex and Series of Mono-Oxo Molybdenum(IV) and Tungsten(IV) Complexes. Structural and Electronic Effects of π-Bonding in trans-[M(O)(X)(dppe)2]+/0 Systems
• Authors of publication: Jesper Bendix; Anders Bøgevig
• Journal of publication: Inorganic Chemistry
• Year of publication: 1998
• Journal volume: 37
• Pages of publication: 5992 - 6001
• a: 9.814 ± 0.005 Å
• b: 22.472 ± 0.003 Å
• c: 21.1029 ± 0.0017 Å
• α: 90°
• β: 92.522 ± 0.017°
• γ: 90°
• Cell volume: 4650 ± 2 ų
• Cell temperature: 122 ± 2 K
• Ambient diffraction temperature: 122 ± 2 K
• Number of distinct elements: 7
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0343
• Residual factor for significantly intense reflections: 0.0306
• Weighted residual factors for significantly intense reflections: 0.062
• Weighted residual factors for all reflections included in the refinement: 0.0636
• Goodness-of-fit parameter for all reflections included in the refinement: 1.178
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No