Information card for entry 4323319

Structure parameters

• Common name: cis,cis-Tetrachloro-bis(dibutylamido)-bis(trimethyl- phosphine) ditungsten(III)
• Chemical name: 1,1,2,2-Tetrachloro-1,2-bis(dibutylamido)-(cis,cis)- 1,2-bis(trimethylphosphine) ditungsten(III)
• Formula: C22 H54 Cl4 N2 P2 W2
• Calculated formula: C22 H54 Cl4 N2 P2 W2
• Title of publication: W2Cl4(NR2)2(PR'3)2 Molecules. 4. A New Synthetic Route to Products with a Staggered Conformation. Preparations and Characterizations of W2Cl4(NR2)2(PR'3)2 (R = Et, Bu, Hex; R'3= Me3, Et2H) and an Intermediate Complex W2Cl4(NEt2)2(NHEt2)2
• Authors of publication: F. Albert Cotton; Evgeny V. Dikarev; N. Nawar; Wai-Yeung Wong
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 559 - 566
• a: 12.162 ± 0.006 Å
• b: 14.955 ± 0.004 Å
• c: 18.82 ± 0.01 Å
• α: 95.66 ± 0.03°
• β: 97.99 ± 0.04°
• γ: 91.26 ± 0.03°
• Cell volume: 3371 ± 3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0827
• Residual factor for significantly intense reflections: 0.0576
• Weighted residual factors for all reflections: 0.1709
• Weighted residual factors for significantly intense reflections: 0.1473
• Goodness-of-fit parameter for all reflections: 1.059
• Goodness-of-fit parameter for significantly intense reflections: 1.037
• Diffraction radiation wavelength: 0.7093 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No