Information card for entry 4323436

Structure parameters

• Common name: trans-Mo(Se)2~2~(dppee)~2~, CH2Cl2
• Chemical name: trans-bis(cis-1,2-bis-(diphenylphosphino)ethylene-P,P')-di-selenido- molybdenum (IV), dichloromethane solvate
• Formula: C53 H46 Cl2 Mo P4 Se2
• Calculated formula: C53 H44 Cl2 Mo P4 Se2
• Title of publication: Mononuclear Molybdenum(IV) Complexes with Two Multiply Bonded Chalcogen Ligands in Trans Configuration and Chelating Biphosphine Ligands
• Authors of publication: F. Albert Cotton; Günter Schmid
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 2267 - 2278
• a: 11.186 ± 0.005 Å
• b: 18.005 ± 0.008 Å
• c: 12.761 ± 0.009 Å
• α: 90°
• β: 110.35 ± 0.04°
• γ: 90°
• Cell volume: 2410 ± 2 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1001
• Residual factor for significantly intense reflections: 0.0653
• Weighted residual factors for all reflections: 0.1684
• Weighted residual factors for significantly intense reflections: 0.1398
• Goodness-of-fit parameter for all reflections: 1.079
• Goodness-of-fit parameter for significantly intense reflections: 1.085
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No