Information card for entry 4323491

Structure parameters

• Chemical name: Bis-(triphenylphospnoranyliden)ammonium tetrakis-difluoromethylargentate(III)
• Formula: C40 H34 Ag F8 N P2
• Calculated formula: C40 H34 Ag F8 N P2
• SMILES: [Ag](C(F)F)(C(F)F)(C(F)F)C(F)F.P(=N[P+](c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Preparation and NMR Spectra of Difluoromethylated Silver(I) and Silver(III) Compounds. Structure of [PNP][Ag(CF~2~H)~4~].
• Authors of publication: Reint Eujen; Berthold Hoge; David J. Brauer
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 3160 - 3166
• a: 9.4748 ± 0.001 Å
• b: 9.4748 ± 0.001 Å
• c: 42.159 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 3784.7 ± 0.8 ų
• Cell temperature: 297 ± 2 K
• Ambient diffraction temperature: 297 ± 2 K
• Number of distinct elements: 6
• Space group number: 78
• Hermann-Mauguin space group symbol: P 43
• Hall space group symbol: P 4cw
• Residual factor for all reflections: 0.0469
• Residual factor for significantly intense reflections: 0.0453
• Weighted residual factors for all reflections: 0.1171
• Weighted residual factors for significantly intense reflections: 0.1155
• Goodness-of-fit parameter for all reflections: 1.008
• Goodness-of-fit parameter for significantly intense reflections: 1.019
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No