Information card for entry 4323753

Structure parameters

• Formula: C52 H58 Br6 Cl4 Hg3 O2 P2 Pd2 S4
• Calculated formula: C52 H58 Br6 Cl4 Hg3 O2 P2 Pd2 S4
• Title of publication: Reactivity of [M(C^P)(S2C-R)] (M = Pd, Pt; C^P = CH2-C6H4-P(o-tolyl)2-κC,P; R = NMe2, OEt) toward HgX2(X = Br, I). X-ray Crystal Structures of [Pt{CH2-C6H4P(o-tolyl)2-κC,P}(S2CNMe2)HgI(μ-I)]2 and [PdBr(S2COEt){μ-P(o-tolyl)2-C6H4-CH2-}HgBr].0.5HgBr2.C2H4Cl2
• Authors of publication: Larry R. Falvello; Juan Forniés; Antonio Martín; Rafael Navarro; Violeta Sicilia; Pablo Villarroya
• Journal of publication: Inorganic Chemistry
• Year of publication: 1997
• Journal volume: 36
• Pages of publication: 6166 - 6171
• a: 15.571 ± 0.002 Å
• b: 10.7425 ± 0.001 Å
• c: 19.6549 ± 0.0015 Å
• α: 90°
• β: 94.741 ± 0.012°
• γ: 90°
• Cell volume: 3276.5 ± 0.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 9
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0735
• Residual factor for significantly intense reflections: 0.041
• Weighted residual factors for all reflections: 0.0964
• Weighted residual factors for significantly intense reflections: 0.0848
• Goodness-of-fit parameter for all reflections: 1.064
• Goodness-of-fit parameter for significantly intense reflections: 1.077
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No