Information card for entry 4324046

Structure parameters

• Common name: Ditechnetium tetrachloro tetra(dimethylphenyl)phosphine hexafluorophosphate
• Chemical name: Ditechnetium tetrachloro tetra(dimethylphenyl)phosphine hexafluorophosphate
• Formula: C32 H44 Cl4 F6 P5 Tc2
• Calculated formula: C32 H44 Cl4 F6 P5 Tc2
• Title of publication: Metal-Metal Multiply-Bonded Complexes of Technetium. 3.1 Preparation and Characterization of Phosphine Complexes of Technetium Possessing a Metal-Metal Bond Order of 3.5
• Authors of publication: F. Albert Cotton; Steven C. Haefner; Alfred P. Sattelberger
• Journal of publication: Inorganic Chemistry
• Year of publication: 1996
• Journal volume: 35
• Pages of publication: 1831 - 1838
• a: 9.4478 ± 0.0011 Å
• b: 24.2995 ± 0.0011 Å
• c: 18.231 ± 0.001 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4185.4 ± 0.6 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 20
• Hermann-Mauguin space group symbol: C 2 2 21
• Hall space group symbol: C 2c 2
• Residual factor for all reflections: 0.0325
• Residual factor for significantly intense reflections: 0.0309
• Weighted residual factors for all reflections: 0.0825
• Weighted residual factors for significantly intense reflections: 0.0812
• Goodness-of-fit parameter for all reflections: 1.107
• Goodness-of-fit parameter for significantly intense reflections: 1.107
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No