Information card for entry 4324879

Structure parameters

• Formula: C100 H190 B2 Cl8 F8 O2 P8 Pt4
• Calculated formula: C100 H190 B2 Cl8 F8 O2 P8 Pt4
• SMILES: [B](F)(F)(F)[F-].O[P](C1CCCCC1)(C1CCCCC1)[Pt]1([PH](C2CCCCC2)C2CCCCC2)[H][Pt]2([P]1(C1CCCCC1)C1CCCCC1)[P](C1CCCCC1)(C1CCCCC1)[Pt]1([P](C3CCCCC3)(C3CCCCC3)[Pt]([P](O)(C3CCCCC3)C3CCCCC3)([PH](C3CCCCC3)C3CCCCC3)[H]1)[P]2(C1CCCCC1)C1CCCCC1.C(Cl)Cl.C(Cl)Cl.[B](F)(F)(F)[F-].C(Cl)Cl.C(Cl)Cl
• Title of publication: Hydrido Phosphanido Bridged Polynuclear Complexes Obtained by Protonation of a Phosphinito Bridged Pt(I) Complex with HBF4 and HF
• Authors of publication: Mario Latronico; Piero Mastrorilli; Vito Gallo; Maria Michela Dell'Anna; Francesco Creati; Nazzareno Re; Ulli Englert
• Journal of publication: Inorganic Chemistry
• Year of publication: 2011
• Journal volume: 50
• Pages of publication: 3539 - 3558
• a: 14.108 ± 0.004 Å
• b: 26.736 ± 0.007 Å
• c: 18.009 ± 0.004 Å
• α: 90°
• β: 121.086 ± 0.017°
• γ: 90°
• Cell volume: 5817 ± 3 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0688
• Residual factor for significantly intense reflections: 0.0452
• Weighted residual factors for significantly intense reflections: 0.092
• Weighted residual factors for all reflections included in the refinement: 0.0998
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No