Information card for entry 4327917

Structure parameters

• Formula: C48 H74 B2 Cl4 F8 Mo2 P2
• Calculated formula: C48 H74 B2 Cl4 F8 Mo2 P2
• SMILES: [B](F)(F)(F)[F-].[c]123[cH]4[cH]5[cH]6[cH]1[MoH]1789%103456([cH]3[c]1([cH]7[c]8([cH]9[c]%103C(C)(C)C)C(C)(C)C)C(C)(C)C)P2P1[c]23[cH]4[cH]5[cH]6[cH]2[MoH]2789%1013456[cH]1[c]%10([cH]9[c]8([cH]7[c]21C(C)(C)C)C(C)(C)C)C(C)(C)C.C(Cl)Cl.[B](F)(F)(F)[F-].C(Cl)Cl
• Title of publication: Symmetrization in a Phosphinidene-Bridged Complex To Give a Diphosphanediyl Derivative with Metal-Centered Reactivity
• Authors of publication: M. Angeles Alvarez; M. Esther García; Daniel García-Vivó; Alberto Ramos; Miguel A. Ruiz; Jaime Suárez
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 34 - 36
• a: 10.193 ± 0.0005 Å
• b: 10.5993 ± 0.0004 Å
• c: 14.6459 ± 0.0006 Å
• α: 83.145 ± 0.003°
• β: 77.047 ± 0.004°
• γ: 62.984 ± 0.004°
• Cell volume: 1373.51 ± 0.11 ų
• Cell temperature: 150.1 K
• Ambient diffraction temperature: 150.1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0554
• Residual factor for significantly intense reflections: 0.0518
• Weighted residual factors for significantly intense reflections: 0.1326
• Weighted residual factors for all reflections included in the refinement: 0.1378
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No