Information card for entry 4327969

Structure parameters

• Formula: C48 H66 La N4 P3 Si4
• Calculated formula: C48 H66 La N4 P3 Si4
• SMILES: [La]1([N](P(c2ccccc2)c2ccccc2)=P(N1P(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(N([Si](C)(C)C)[Si](C)(C)C)N([Si](C)(C)C)[Si](C)(C)C
• Title of publication: The Intramolecular Rearrangement of Phosphinohydrazides [R'2P-NR-NR-M] →[RN=PR'2-NR-M]: General Rules and Exceptions. Transformations of Bulky Phosphinohydrazines (R-NH-N(PPh2)2, R =tBu, Ph2P)
• Authors of publication: Alexander N. Kornev; Vyacheslav V. Sushev; Yulia S. Panova; Natalia V. Belina; Olga V. Lukoyanova; Georgy K. Fukin; Sergey Y. Ketkov; Gleb A. Abakumov; Peter Lönnecke; Evamarie Hey-Hawkins
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 874 - 881
• a: 11.5932 ± 0.0004 Å
• b: 12.2192 ± 0.0004 Å
• c: 20.8318 ± 0.0006 Å
• α: 86.39 ± 0.001°
• β: 84.327 ± 0.001°
• γ: 63.19 ± 0.001°
• Cell volume: 2620.35 ± 0.15 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0374
• Residual factor for significantly intense reflections: 0.0305
• Weighted residual factors for significantly intense reflections: 0.0718
• Weighted residual factors for all reflections included in the refinement: 0.0745
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No