Information card for entry 4328145

Structure parameters

• Common name: (tBuClip)Mo(μ-N)(μ-NH2)Mo(tBuClip) . 0.5 Et2O
• Chemical name: (μ-Nitrido)(μ-amido)bis(4,4'-Di-tert-butylbiphenyl-2,2'-bis((2-oxy- 3,5-di-tert-butylphenyl)amido)dimolybdenum(VI) hemidiethylether solvate
• Formula: C98 H135 Mo2 N6 O4.5
• Calculated formula: C98 H135 Mo2 N6 O4.5
• Title of publication: Molybdenum(VI) Complexes of a 2,2'-Biphenyl-bridged Bis(amidophenoxide): Competition between Metal-Ligand and Metal-Amidophenoxide π Bonding
• Authors of publication: Jason A. Kopec; Sukesh Shekar; Seth N. Brown
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 1239 - 1250
• a: 14.7223 ± 0.0002 Å
• b: 15.4117 ± 0.0003 Å
• c: 21.2348 ± 0.0004 Å
• α: 88.7516 ± 0.0008°
• β: 84.1354 ± 0.0008°
• γ: 75.381 ± 0.0007°
• Cell volume: 4637.66 ± 0.14 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0438
• Residual factor for significantly intense reflections: 0.0352
• Weighted residual factors for significantly intense reflections: 0.0898
• Weighted residual factors for all reflections included in the refinement: 0.0953
• Goodness-of-fit parameter for all reflections included in the refinement: 1.017
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No