Information card for entry 4329997

Structure parameters

• Formula: C39 H50 Ag F5 Ge N4 Si
• Calculated formula: C39 H50 Ag F5 Ge N4 Si
• SMILES: [Ag]([Ge]1(N(C(=CC(=[N]1c1c(cccc1C(C)C)C(C)C)C)C)c1c(cccc1C(C)C)C(C)C)C([Si](C)(C)C)=N#N)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: β-Diketiminate Germylene-Supported Pentafluorophenylcopper(I) and -silver(I) Complexes [LGe(Me)(CuC6F5)n]2 (n = 1, 2), LGe[C(SiMe3)N2]AgC6F5, and {LGe[C(SiMe3)N2](AgC6F5)2}2 (L = HC[C(Me)N-2,6-iPr2C6H3]2): Synthesis and Structural Characterization
• Authors of publication: Na Zhao; Jinyuan Zhang; Ying Yang; Hongping Zhu; Yan Li; Gang Fu
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 8710 - 8718
• a: 11.3442 ± 0.0003 Å
• b: 17.0271 ± 0.0005 Å
• c: 21.549 ± 0.0005 Å
• α: 90°
• β: 102.671 ± 0.002°
• γ: 90°
• Cell volume: 4061.01 ± 0.19 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0626
• Residual factor for significantly intense reflections: 0.0316
• Weighted residual factors for significantly intense reflections: 0.0519
• Weighted residual factors for all reflections included in the refinement: 0.0552
• Goodness-of-fit parameter for all reflections included in the refinement: 0.795
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No