Information card for entry 4330890

Structure parameters

• Formula: C21 H35 N2 Rh Si2
• Calculated formula: C21 H35 N2 Rh Si2
• SMILES: [Rh]1234(N([Si](C)(C)C)C(=[N]1[Si](C)(C)C)c1ccccc1)[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Bis(amidinato)germylenerhodium Complexes: Synthesis, Structure, and Density Functional Theory Calculations
• Authors of publication: Dimitri Matioszek; Nathalie Saffon; Jean-Marc Sotiropoulos; Karinne Miqueu; Annie Castel; Jean Escudié
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 11716 - 11721
• a: 6.6791 ± 0.0002 Å
• b: 9.7861 ± 0.0004 Å
• c: 34.6517 ± 0.0013 Å
• α: 90°
• β: 94.379 ± 0.002°
• γ: 90°
• Cell volume: 2258.3 ± 0.14 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 5
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 n 1
• Hall space group symbol: P -2yac
• Residual factor for all reflections: 0.0491
• Residual factor for significantly intense reflections: 0.0382
• Weighted residual factors for significantly intense reflections: 0.0681
• Weighted residual factors for all reflections included in the refinement: 0.0715
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No