Information card for entry 4331202

Structure parameters

• Formula: C30 H35 Co N5 Si
• Calculated formula: C30 H35 Co N5 Si
• SMILES: [Co]12(N3C(=Nc4[n]2c2c(c(c4)C)CCC2)c2c(C3=Nc3[n]1c1c(c(c3)C)CCC1)cccc2)C[Si](C)(C)C
• Title of publication: Cobalt Alkyl Complexes of a New Family of Chiral 1,3-Bis(2-pyridylimino)isoindolates and Their Application in Asymmetric Hydrosilylation
• Authors of publication: Désirée C. Sauer; Hubert Wadepohl; Lutz H. Gade
• Journal of publication: Inorganic Chemistry
• Year of publication: 2012
• Journal volume: 51
• Pages of publication: 12948 - 12958
• a: 10.5259 ± 0.0008 Å
• b: 11.7868 ± 0.0017 Å
• c: 12.0577 ± 0.0018 Å
• α: 87.707 ± 0.012°
• β: 68.561 ± 0.01°
• γ: 76.285 ± 0.009°
• Cell volume: 1350.9 ± 0.3 ų
• Cell temperature: 109.96 ± 0.14 K
• Ambient diffraction temperature: 109.96 ± 0.14 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1126
• Residual factor for significantly intense reflections: 0.0895
• Weighted residual factors for significantly intense reflections: 0.2138
• Weighted residual factors for all reflections included in the refinement: 0.2301
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No