Information card for entry 4331754

Structure parameters

• Chemical name: η^2^-[1,1,1,3,3,5,5,5-Octamethyl-2,4-bis(trimethylsilyl)pentasilane- 2,4-diolato]-η^2^-dichloro- η^1^-tetrachloro-dititanium
• Formula: C14 H42 Cl6 O2 Si7 Ti2
• Calculated formula: C14 H42 Cl6 O2 Si7 Ti2
• Title of publication: Trisilane-1,3-diolato Complexes of Ti and Zr: Syntheses and X-ray Crystal Structures†
• Authors of publication: Krempner, C.; Köckerling, M.; Reinke, H.; Weichert, K.
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 8
• Pages of publication: 3203 - 3211
• a: 12.3918 ± 0.0004 Å
• b: 16.855 ± 0.0005 Å
• c: 18.0253 ± 0.0005 Å
• α: 90°
• β: 106.144 ± 0.001°
• γ: 90°
• Cell volume: 3616.37 ± 0.19 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0218
• Residual factor for significantly intense reflections: 0.02
• Weighted residual factors for significantly intense reflections: 0.0519
• Weighted residual factors for all reflections included in the refinement: 0.0532
• Goodness-of-fit parameter for all reflections included in the refinement: 1.061
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No