Information card for entry 4332103

Structure parameters

• Formula: C43 H61 Cl Ga N2 Rh
• Calculated formula: C43 H61 Cl Ga N2 Rh
• SMILES: CC(c1c(c(C(C)C)ccc1)N1[Ga]([Rh]234567([CH]8CCCCCC[CH]2=8)[cH]2[cH]5[cH]6[cH]7[cH]4[cH]32)(Cl)[N](=C(C=C1C)C)c1c(cccc1C(C)C)C(C)C)C
• Title of publication: Insertion of the Ga(I) Bis-imidinate Ga(DDP) into the Metal Halogen Bonds of Rh(I) Complexes. How Electrophilic Are Coordinated Ga(DDP) Fragments?†
• Authors of publication: Kempter, Andreas; Gemel, Christian; Hardman, Ned J.; Fischer, Roland A.
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 7
• Pages of publication: 3133 - 3138
• a: 10.487 ± 0.005 Å
• b: 11.495 ± 0.005 Å
• c: 16.571 ± 0.004 Å
• α: 87.85 ± 0.03°
• β: 87.03 ± 0.03°
• γ: 76.08 ± 0.04°
• Cell volume: 1935.7 ± 1.4 ų
• Cell temperature: 105 ± 2 K
• Ambient diffraction temperature: 105 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0625
• Residual factor for significantly intense reflections: 0.0416
• Weighted residual factors for significantly intense reflections: 0.0878
• Weighted residual factors for all reflections included in the refinement: 0.0948
• Goodness-of-fit parameter for all reflections included in the refinement: 0.954
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No