Information card for entry 4332474

Structure parameters

• Chemical name: Tetrakis(Tetraamminelithium)Tetradekaphosphide-Ammonia(1/1)
• Formula: H54 Li4 N18 P14
• Calculated formula: H54 Li4 N18 P14
• SMILES: [NH3][Li]([NH3])([NH3])[NH3].[NH3][Li]([NH3])([NH3])[NH3].N.P12P(P3P([P-]1)P3[P-]2)P1P2[P-]P3P1P3[P-]2.[NH3][Li]([NH3])([NH3])[NH3].N.[NH3][Li]([NH3])([NH3])[NH3]
• Title of publication: Dimers of Heptapnictide Anions: As144-and P144-in the Crystal Structures of [Rb(18-crown-6)]4As14·6NH3and [Li(NH3)4]4P14·NH3
• Authors of publication: Hanauer, Tobias; Aschenbrenner, Jürgen C.; Korber, Nikolaus
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 17
• Pages of publication: 6723 - 6727
• a: 9.283 ± 0.003 Å
• b: 9.508 ± 0.003 Å
• c: 13.466 ± 0.004 Å
• α: 99.24 ± 0.03°
• β: 91.66 ± 0.03°
• γ: 118.45 ± 0.03°
• Cell volume: 1023.8 ± 0.6 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0568
• Residual factor for significantly intense reflections: 0.0409
• Weighted residual factors for significantly intense reflections: 0.1006
• Weighted residual factors for all reflections included in the refinement: 0.105
• Goodness-of-fit parameter for all reflections included in the refinement: 0.934
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No