Information card for entry 4333068

Structure parameters

• Common name: [Mo2(DmCF3F)3]2(OH)2,CH2Cl2
• Formula: C91 H56 Cl2 F36 Mo4 N12 O2
• Calculated formula: C91 H56 Cl2 F36 Mo4 N12 O2
• Title of publication: A Rare and Highly Oxidized Mo25.5+Unit Stabilized by Oxo Anions and Supported by Formamidinate Bridges
• Authors of publication: Cotton, F. Albert; Murillo, Carlos A.; Yu, Rongmin; Zhao, Qinliang
• Journal of publication: Inorganic Chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 22
• Pages of publication: 9046 - 9052
• a: 13.902 ± 0.003 Å
• b: 14.435 ± 0.003 Å
• c: 14.909 ± 0.003 Å
• α: 64.168 ± 0.003°
• β: 79.495 ± 0.003°
• γ: 62.515 ± 0.003°
• Cell volume: 2388.3 ± 0.9 ų
• Cell temperature: 213 ± 2 K
• Ambient diffraction temperature: 213 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0663
• Residual factor for significantly intense reflections: 0.0501
• Weighted residual factors for significantly intense reflections: 0.1301
• Weighted residual factors for all reflections included in the refinement: 0.1431
• Goodness-of-fit parameter for all reflections included in the refinement: 1.043
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No