Synthesis and Catalytic Epoxidation Activity with TBHP and H2O2of Dioxo-, Oxoperoxo-, and Oxodiperoxo Molybdenum(VI) and Tungsten(VI) Compounds Containing Monodentate or Bidentate Phosphine Oxide Ligands: Crystal Structures of WCl2(O)2(OPMePh2)2, WCl2(O)(O2)(OPMePh2)2, MoCl2(O)2dppmO2·C4H10O, WCl2(O)2dppmO2, Mo(O)(O2)2dppmO2, and W(O)(O2)2dppmO2
Authors of publication
Jimtaisong, Ampa; Luck, Rudy L.
Journal of publication
Inorganic Chemistry
Year of publication
2006
Journal volume
45
Journal issue
25
Pages of publication
10391 - 10402
a
13.519 ± 0.002 Å
b
10.978 ± 0.003 Å
c
17.159 ± 0.003 Å
α
90°
β
96.3 ± 0.01°
γ
90°
Cell volume
2531.2 ± 0.9 Å3
Cell temperature
293 ± 2 K
Ambient diffraction temperature
293 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.1276
Residual factor for significantly intense reflections
0.0669
Weighted residual factors for significantly intense reflections
0.1312
Weighted residual factors for all reflections included in the refinement
0.1509
Goodness-of-fit parameter for all reflections included in the refinement
