Information card for entry 4333223

Structure parameters

• Formula: C24 H58 N2 O3 Os P4 S5
• Calculated formula: C24 H58 N2 O3 Os P4 S5
• SMILES: [Os]12([S]=P(N=P(S1)(C(C)C)C(C)C)(C(C)C)C(C)C)([S]=P(N=P(S2)(C(C)C)C(C)C)(C(C)C)C(C)C)([S](=O)=O)[OH2]
• Title of publication: Synthesis, crystal structures, and reactivity of osmium(II) and -(IV) complexes containing a dithioimidodiphosphinate ligand.
• Authors of publication: Cheung, Wai-Man; Zhang, Qian-Feng; Williams, Ian D.; Leung, Wa-Hung
• Journal of publication: Inorganic chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 14
• Pages of publication: 5754 - 5762
• a: 9.922 ± 0.006 Å
• b: 14.963 ± 0.009 Å
• c: 26.216 ± 0.015 Å
• α: 90°
• β: 94.05 ± 0.014°
• γ: 90°
• Cell volume: 3882 ± 4 ų
• Cell temperature: 298 ± 2 K
• Ambient diffraction temperature: 298 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0824
• Residual factor for significantly intense reflections: 0.0532
• Weighted residual factors for significantly intense reflections: 0.0906
• Weighted residual factors for all reflections included in the refinement: 0.1037
• Goodness-of-fit parameter for all reflections included in the refinement: 0.983
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No