Information card for entry 4333324

Structure parameters

• Common name: [Ru(η^5^-C~5~Me~5~){P^i^Pr~2~NC~6~H~10~NP^i^Pr~2~-κ^3^-P,P',N}] [B{C~8~H~3~F~6~}~4~]'
• Chemical name: pentahapto-pentamethylcyclopentadienyl-{(R,R)-bis((diisopropylphosphino)amino) cyclohexane-κ^3^-P,P',N}ruthenium(II) tetrakis{3,5-bis(trifluoromethyl)phenyl} borate
• Formula: C60 H67 B F24 N2 P2 Ru
• Calculated formula: C60 H67 B F24 N2 P2 Ru
• Title of publication: Coordinatively Unsaturated Semisandwich Complexes of Ruthenium with Phosphinoamine Ligands and Related Species: A Complex Containing (R,R)-1,2-Bis((diisopropylphosphino)amino)cyclohexane in a New Coordination Form κ3P,P‘,N-η2-P,N
• Authors of publication: Palacios, M. Dolores; Puerta, M. Carmen; Valerga, Pedro; Lledós, Agustí; Veilly, Edouard
• Journal of publication: Inorganic Chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 17
• Pages of publication: 6958 - 6967
• a: 13.259 ± 0.003 Å
• b: 13.256 ± 0.003 Å
• c: 17.905 ± 0.004 Å
• α: 90°
• β: 92.74 ± 0.03°
• γ: 90°
• Cell volume: 3143.4 ± 1.2 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0408
• Residual factor for significantly intense reflections: 0.0401
• Weighted residual factors for significantly intense reflections: 0.0869
• Weighted residual factors for all reflections included in the refinement: 0.0874
• Goodness-of-fit parameter for all reflections included in the refinement: 1.047
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No