Information card for entry 4333326

Structure parameters

• Common name: [Ru(η^5^-C~5~Me~5~){P^i^Pr~2~NHCH~2~CH~2~NHP^i^Pr~2~-κ^2^-P,P'}(η^2^-O~2~)] [B{C~8~H~3~F~6~}~4~]
• Chemical name: pentahapto-pentamethylcyclopentadienyl-{bis((diisopropylphosphino)amino) ethane-κ^2^-P,P'}-dihapto-dioxygen-ruthenium (II) tetrakis{3,5-bis(trifluoromethyl)phenyl}borate
• Formula: C56 H61 B F24 N2 O2 P2 Ru
• Calculated formula: C56 H61 B F24 N2 O2 P2 Ru
• Title of publication: Coordinatively Unsaturated Semisandwich Complexes of Ruthenium with Phosphinoamine Ligands and Related Species: A Complex Containing (R,R)-1,2-Bis((diisopropylphosphino)amino)cyclohexane in a New Coordination Form κ3P,P‘,N-η2-P,N
• Authors of publication: Palacios, M. Dolores; Puerta, M. Carmen; Valerga, Pedro; Lledós, Agustí; Veilly, Edouard
• Journal of publication: Inorganic Chemistry
• Year of publication: 2007
• Journal volume: 46
• Journal issue: 17
• Pages of publication: 6958 - 6967
• a: 14.176 ± 0.003 Å
• b: 14.483 ± 0.003 Å
• c: 15.648 ± 0.003 Å
• α: 98.52 ± 0.03°
• β: 102.84 ± 0.03°
• γ: 100.43 ± 0.03°
• Cell volume: 3020.6 ± 1.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0693
• Residual factor for significantly intense reflections: 0.0594
• Weighted residual factors for significantly intense reflections: 0.112
• Weighted residual factors for all reflections included in the refinement: 0.1172
• Goodness-of-fit parameter for all reflections included in the refinement: 1.076
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No