Information card for entry 4334680

Structure parameters

• Chemical name: N,N-bis(trimethylsilyl)amino(4-dimethylaminopyridyl)azidophosphenium tetrachlorogallate
• Formula: C13 H28 Cl4 Ga N6 P Si2
• Calculated formula: C13 H28 Cl4 Ga N6 P Si2
• SMILES: P(N=N#N)(N([Si](C)(C)C)[Si](C)(C)C)[n+]1ccc(N(C)C)cc1.[Ga](Cl)(Cl)(Cl)[Cl-]
• Title of publication: On the Synthesis and Reactivity of Highly Labile Pseudohalogen Phosphenium Ions
• Authors of publication: Christian Hering; Axel Schulz; Alexander Villinger
• Journal of publication: Inorganic Chemistry
• Year of publication: 2013
• Journal volume: 52
• Pages of publication: 5214 - 5225
• a: 9.9817 ± 0.0003 Å
• b: 26.1792 ± 0.0008 Å
• c: 10.069 ± 0.0003 Å
• α: 90°
• β: 95.644 ± 0.002°
• γ: 90°
• Cell volume: 2618.4 ± 0.14 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0709
• Residual factor for significantly intense reflections: 0.0347
• Weighted residual factors for significantly intense reflections: 0.0644
• Weighted residual factors for all reflections included in the refinement: 0.0758
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No