Information card for entry 4337397

Structure parameters

• Chemical name: Bis((2,4,6,2'',4'',6''-hexamethyl-1,1':3';1''-terphenyl- 2')amido)tetramethyldisilazanido-N,N',N"-cerium sesqui(tetrahydrofuran)solvate
• Formula: C58 H74 Ce N3 O1.5 Si2
• Calculated formula: C58 H74 Ce N3 O1.5 Si2
• Title of publication: Formation of Novel T-Shaped NNN Ligands via Rare-Earth Metal-Mediated Si-H Activation.
• Authors of publication: Bubrin, Denis; Niemeyer, Mark
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 3
• Pages of publication: 1269 - 1271
• a: 10.0648 ± 0.0004 Å
• b: 10.7357 ± 0.0004 Å
• c: 27.2474 ± 0.0011 Å
• α: 81.559 ± 0.002°
• β: 80.336 ± 0.002°
• γ: 64.769 ± 0.002°
• Cell volume: 2616.12 ± 0.18 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0562
• Residual factor for significantly intense reflections: 0.0463
• Weighted residual factors for significantly intense reflections: 0.1055
• Weighted residual factors for all reflections included in the refinement: 0.108
• Goodness-of-fit parameter for all reflections included in the refinement: 1.459
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No