Information card for entry 4338124

Structure parameters

• Formula: C69 H44 B Cl2 F24 N O3 P2 W2
• Calculated formula: C69 H44 B Cl2 F24 N O3 P2 W2
• Title of publication: Reactions of the Unsaturated Ditungsten Complexes [W2Cp2(μ-PPh2)2(CO)x] (x = 1, 2) with Nitric Oxide: Stereoselective Carbonyl Displacement and Oxygen-Transfer Reactions of a Nitrite Ligand.
• Authors of publication: Alvarez, M. Angeles; García, M Esther; García-Vivó, Daniel; Melón, Sonia; Ruiz, Miguel A.; Toyos, Adrián
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 9
• Pages of publication: 4739 - 4750
• a: 11.6012 ± 0.0004 Å
• b: 16.5397 ± 0.0004 Å
• c: 18.9692 ± 0.0003 Å
• α: 81.1647 ± 0.0018°
• β: 83.415 ± 0.002°
• γ: 76.575 ± 0.002°
• Cell volume: 3486.51 ± 0.16 ų
• Cell temperature: 130 ± 7 K
• Ambient diffraction temperature: 130 ± 7 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0495
• Residual factor for significantly intense reflections: 0.0437
• Weighted residual factors for significantly intense reflections: 0.1129
• Weighted residual factors for all reflections included in the refinement: 0.1188
• Goodness-of-fit parameter for all reflections included in the refinement: 1.05
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No