Information card for entry 4338590

Structure parameters

• Formula: C18 H25 N2 P
• Calculated formula: C18 H25 N2 P
• SMILES: P(N(Nc1ccccc1)c1ccccc1)(C(C)C)C(C)C
• Title of publication: The First Structurally Characterized Metal (κ^2^N,P)-Phosphinohydrazides: The Key to Understanding the Intramolecular Rearrangement R~2~P–NR'–NR'–M → R'N=PR~2~–NR'–M. Metalloderivatives of Diisopropylphosphinohydrazines: Synthesis and Properties
• Authors of publication: Kornev, Alexander N.; Belina, Natalia V.; Sushev, Vyacheslav V.; Fukin, Georgy K.; Baranov, Evgenii V.; Kurskiy, Yuriy A.; Poddelskii, Andrei I.; Abakumov, Gleb A.; Lönnecke, Peter; Hey-Hawkins, Evamarie
• Journal of publication: Inorganic chemistry
• Year of publication: 2009
• Journal volume: 48
• Journal issue: 12
• Pages of publication: 5574 - 5583
• a: 8.5892 ± 0.0003 Å
• b: 11.3094 ± 0.0004 Å
• c: 9.0016 ± 0.0003 Å
• α: 90°
• β: 101.894 ± 0.001°
• γ: 90°
• Cell volume: 855.63 ± 0.05 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 4
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0264
• Residual factor for significantly intense reflections: 0.0262
• Weighted residual factors for significantly intense reflections: 0.069
• Weighted residual factors for all reflections included in the refinement: 0.0693
• Goodness-of-fit parameter for all reflections included in the refinement: 1.058
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No