Information card for entry 4338615

Structure parameters

• Common name: Moris-194 (Sinay)
• Formula: C21 H27 F5 Li N5 Si
• Calculated formula: C21 H27 F5 Li N5 Si
• SMILES: [Si](/N=C/1N(c2c(F)c(F)c(F)c(F)c2F)[Li]2([n]3c1cccc3)[N](C=C[N]2(C)C)(C)C)(C)(C)C
• Title of publication: Synthesis of Lithium N-pentafluorophenyl,N'-trimethylsilyl 2-Pyridylamidinate and Its Cyclization to Lithium Tetrafluoro-2-(2-pyridyl)benzimidazolate via a Me3SiF Elimination. Coordination Chemistry, Reactivity, and Mechanism
• Authors of publication: Aharonovich, Sinai; Botoshanski, Mark; Eisen, Moris S.
• Journal of publication: Inorganic chemistry
• Year of publication: 2009
• Journal volume: 48
• Journal issue: 12
• Pages of publication: 5269 - 5278
• a: 10.987 ± 0.002 Å
• b: 17.479 ± 0.003 Å
• c: 14.737 ± 0.003 Å
• α: 90°
• β: 113.47 ± 0.03°
• γ: 90°
• Cell volume: 2596 ± 1 ų
• Cell temperature: 240 ± 2 K
• Ambient diffraction temperature: 240 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1854
• Residual factor for significantly intense reflections: 0.0677
• Weighted residual factors for significantly intense reflections: 0.1635
• Weighted residual factors for all reflections included in the refinement: 0.2017
• Goodness-of-fit parameter for all reflections included in the refinement: 0.9
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No