Information card for entry 4340183

Structure parameters

• Formula: C24 H34 Cl2 N14 O11 S4 V2
• Calculated formula: C24 H34 Cl2 N14 O11 S4 V2
• Title of publication: Unprecedented [V2O]6+ core of a centrosymmetric thiosemicarbazonato dimer: spontaneous deoxygenation of oxovanadium(IV).
• Authors of publication: Shongwe, Musa S.; Al-Kharousi, Huda N R; Adams, Harry; Morris, Michael J.; Bill, Eckhard
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 3
• Pages of publication: 1103 - 1107
• a: 9.286 ± 0.003 Å
• b: 9.478 ± 0.003 Å
• c: 21.541 ± 0.006 Å
• α: 90°
• β: 96.008 ± 0.005°
• γ: 90°
• Cell volume: 1885.5 ± 1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1365
• Residual factor for significantly intense reflections: 0.0738
• Weighted residual factors for significantly intense reflections: 0.1705
• Weighted residual factors for all reflections included in the refinement: 0.1961
• Goodness-of-fit parameter for all reflections included in the refinement: 0.95
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No