Information card for entry 4341039

Structure parameters

• Formula: C29 H52 Co N P2 Si
• Calculated formula: C29 H52 Co N P2 Si
• SMILES: c12cccc3C[P](C(C)(C)C)(C(C)(C)C)[CoH2]([n]23)([SiH2]c2ccccc2)[P](C1)(C(C)(C)C)C(C)(C)C
• Title of publication: Carbon dioxide hydrosilylation promoted by cobalt pincer complexes.
• Authors of publication: Scheuermann, Margaret L.; Semproni, Scott P.; Pappas, Iraklis; Chirik, Paul J.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 18
• Pages of publication: 9463 - 9465
• a: 10.728 ± 0.005 Å
• b: 17.553 ± 0.005 Å
• c: 17.57 ± 0.005 Å
• α: 76.26 ± 0.005°
• β: 84.341 ± 0.005°
• γ: 73.316 ± 0.005°
• Cell volume: 3077 ± 1.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0334
• Residual factor for significantly intense reflections: 0.0303
• Weighted residual factors for significantly intense reflections: 0.0737
• Weighted residual factors for all reflections included in the refinement: 0.0755
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation wavelength: 1.54185 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No