Information card for entry 4341328

Structure parameters

• Formula: C144 H120 Cl2 Eu6 Li4 O20 Si12
• Calculated formula: C144 H120 Cl2 Eu6 Li4 O20 Si12
• SMILES: [Eu]12345[O]6[Li]7[O]82[Eu]29[O]%10([Eu]%11[O]49[Eu]49%12%13[O]%14[Li]%15[O]9([Eu]9%16[O]%17([Li]([O]1[Si](O[Si]6(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[O]3([Si](O[Si]8(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[Eu]%17[O]5%13%16)[Si](O[Si]([O]%159)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[Si](O[Si]([O]%11%12[Li]%10[O]4[Si](O[Si]%14(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[Si](O[Si]([O]72)(c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1.[Cl-].[Cl-]
• Title of publication: Heterometallic europium disiloxanediolates: synthesis, structural diversity, and photoluminescence properties.
• Authors of publication: Rausch, Janek; Lorenz, Volker; Hrib, Cristian G.; Frettlöh, Vanessa; Adlung, Matthias; Wickleder, Claudia; Hilfert, Liane; Jones, Peter G.; Edelmann, Frank T.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 21
• Pages of publication: 11662 - 11674
• a: 14.3252 ± 0.0008 Å
• b: 16.91 ± 0.0008 Å
• c: 17.9276 ± 0.0008 Å
• α: 85.008 ± 0.004°
• β: 86.407 ± 0.004°
• γ: 74.361 ± 0.004°
• Cell volume: 4162.6 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0753
• Residual factor for significantly intense reflections: 0.0417
• Weighted residual factors for significantly intense reflections: 0.089
• Weighted residual factors for all reflections included in the refinement: 0.0971
• Goodness-of-fit parameter for all reflections included in the refinement: 0.839
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No