Information card for entry 4341490

Structure parameters

• Formula: C32 H83 K N3 O6.5 Si6 Te2 U
• Calculated formula: C32 H78 K N3 O6.5 Si6 Te2 U
• Title of publication: Synthesis of terminal monochalcogenide and dichalcogenide complexes of uranium using polychalcogenides, [en](2-) (e = te, N = 2; e = se, N = 4), as chalcogen atom transfer reagents.
• Authors of publication: Smiles, Danil E.; Wu, Guang; Hayton, Trevor W.
• Journal of publication: Inorganic chemistry
• Year of publication: 2014
• Journal volume: 53
• Journal issue: 19
• Pages of publication: 10240 - 10247
• a: 11.1133 ± 0.0012 Å
• b: 14.6606 ± 0.0017 Å
• c: 17.909 ± 0.002 Å
• α: 88.872 ± 0.002°
• β: 88.828 ± 0.002°
• γ: 69.715 ± 0.002°
• Cell volume: 2736.1 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0366
• Residual factor for significantly intense reflections: 0.0272
• Weighted residual factors for significantly intense reflections: 0.0562
• Weighted residual factors for all reflections included in the refinement: 0.0609
• Goodness-of-fit parameter for all reflections included in the refinement: 1.008
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No