Synthesis, Structure, and Magnetism of a Family of Heterometallic {Cu2Ln7} and {Cu4Ln12} (Ln = Gd, Tb, and Dy) Complexes: The Gd Analogues Exhibiting a Large Magnetocaloric Effect
Authors of publication
Langley, Stuart K.; Moubaraki, Boujemaa; Tomasi, Corrado; Evangelisti, Marco; Brechin, Euan K.; Murray, Keith S.
Journal of publication
Inorganic Chemistry
Year of publication
2014
Pages of publication
141119100121008
a
32.1 ± 0.006 Å
b
11.9 ± 0.002 Å
c
29.42 ± 0.006 Å
α
90°
β
90°
γ
90°
Cell volume
11238 ± 4 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
7
Space group number
29
Hermann-Mauguin space group symbol
P c a 21
Hall space group symbol
P 2c -2ac
Residual factor for all reflections
0.0377
Residual factor for significantly intense reflections
0.037
Weighted residual factors for significantly intense reflections
0.1071
Weighted residual factors for all reflections included in the refinement
0.1076
Goodness-of-fit parameter for all reflections included in the refinement
