Information card for entry 4342781

Structure parameters

• Formula: C43 H34 Cl F7 P3 Sb
• Calculated formula: C43 H34 Cl F7 P3 Sb
• SMILES: C(=P(c1ccccc1)(c1ccccc1)c1ccccc1)([P+](c1ccccc1)(c1ccccc1)c1ccccc1)P(c1ccc(cc1)F)Cl.F[Sb](F)(F)(F)(F)[F-]
• Title of publication: C-f bond activation by transient phosphenium dications.
• Authors of publication: Đorđević, Nemanja; Tay, Madelyn Qin Yi; Muthaiah, Senthilkumar; Ganguly, Rakesh; Dimić, Dušan; Vidović, Dragoslav
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 9
• Pages of publication: 4180 - 4182
• a: 11.7973 ± 0.0004 Å
• b: 13.4325 ± 0.0005 Å
• c: 13.4603 ± 0.0005 Å
• α: 89.7362 ± 0.0013°
• β: 79.2458 ± 0.0013°
• γ: 66.808 ± 0.0012°
• Cell volume: 1920.6 ± 0.12 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0293
• Residual factor for significantly intense reflections: 0.0244
• Weighted residual factors for significantly intense reflections: 0.0591
• Weighted residual factors for all reflections included in the refinement: 0.0616
• Goodness-of-fit parameter for all reflections included in the refinement: 1.032
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No