Information card for entry 4346039

Structure parameters

• Formula: C37 H56 Ge2 N4 O3 Ru
• Calculated formula: C37 H56 Ge2 N4 O3 Ru
• SMILES: CC(N1C(c2ccccc2)=[N](C(C)C)[Ge]1([Ru](C#[O])(C#[O])([Ge]1([N](C(C)C)=C(c2ccccc2)N1C(C)C)C(C)(C)C)C#[O])C(C)(C)C)C
• Title of publication: Amidinatogermylene derivatives of ruthenium carbonyl: new insights into the reactivity of [Ru3(CO)12] with two-electron-donor reagents of high basicity.
• Authors of publication: Álvarez-Rodríguez, Lucía; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Polo, Diego
• Journal of publication: Inorganic chemistry
• Year of publication: 2015
• Journal volume: 54
• Journal issue: 6
• Pages of publication: 2983 - 2994
• a: 12.9544 ± 0.0004 Å
• b: 17.2117 ± 0.0005 Å
• c: 19.2876 ± 0.0008 Å
• α: 90°
• β: 108.421 ± 0.004°
• γ: 90°
• Cell volume: 4080.1 ± 0.3 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.0407
• Residual factor for significantly intense reflections: 0.033
• Weighted residual factors for significantly intense reflections: 0.087
• Weighted residual factors for all reflections included in the refinement: 0.0933
• Goodness-of-fit parameter for all reflections included in the refinement: 1.06
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No