Quasi-three-coordinate iron and cobalt terphenoxide complexes {Ar(iPr8)OM(μ-O)}2 (Ar(iPr8) = C6H-2,6-(C6H2-2,4,6-(i)Pr3)2-3,5-(i)Pr2; M = Fe or Co) with M(III)2(μ-O)2 core structures and the peroxide dimer of 2-oxepinoxy relevant to benzene oxidation.
Authors of publication
Zhao, Pei; Lei, Hao; Ni, Chengbao; Guo, Jing-Dong; Kamali, Saeed; Fettinger, James C.; Grandjean, Fernande; Long, Gary J.; Nagase, Shigeru; Power, Philip P.
Journal of publication
Inorganic chemistry
Year of publication
2015
Journal volume
54
Journal issue
18
Pages of publication
8914 - 8922
a
18.719 ± 0.0017 Å
b
19.0419 ± 0.0017 Å
c
27.187 ± 0.002 Å
α
90°
β
104.993 ± 0.001°
γ
90°
Cell volume
9360.8 ± 1.4 Å3
Cell temperature
90 ± 2 K
Ambient diffraction temperature
90 ± 2 K
Number of distinct elements
4
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.1525
Residual factor for significantly intense reflections
0.0596
Weighted residual factors for significantly intense reflections
0.1411
Weighted residual factors for all reflections included in the refinement
0.1662
Goodness-of-fit parameter for all reflections included in the refinement
