Information card for entry 4347330

Structure parameters

• Formula: C30 H47 Cl2 N Si
• Calculated formula: C30 H47 Cl2 N Si
• SMILES: [Si](Cl)(Cl)(C1(C)C(=C(C)C(=C1C)C)C)[C@H]1C(C)(C)CC(C)(C)N1c1c(C(C)C)cccc1C(C)C
• Title of publication: Insertion of Cyclic Alkyl(amino) Carbene into the Si-H Bonds of Hydrochlorosilanes.
• Authors of publication: Mohapatra, Chandrajeet; Samuel, Prinson P.; Li, Bin; Niepötter, Benedikt; Schürmann, Christian J; Herbst-Irmer, Regine; Stalke, Dietmar; Maity, Bholanath; Koley, Debasis; Roesky, Herbert W.
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 5
• Pages of publication: 1953 - 1955
• a: 8.815 ± 0.002 Å
• b: 16.427 ± 0.003 Å
• c: 10.972 ± 0.002 Å
• α: 90°
• β: 113.64 ± 0.02°
• γ: 90°
• Cell volume: 1455.5 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0293
• Residual factor for significantly intense reflections: 0.0263
• Weighted residual factors for significantly intense reflections: 0.0617
• Weighted residual factors for all reflections included in the refinement: 0.0632
• Goodness-of-fit parameter for all reflections included in the refinement: 1.025
• Diffraction radiation wavelength: 0.56086 Å
• Diffraction radiation type: AgKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No