Efficient Ni(II)2Ln(III)2 Electrocyclization Catalysts for the Synthesis of trans-4,5-Diaminocyclopent-2-enones from 2-Furaldehyde and Primary or Secondary Amines.
Authors of publication
Griffiths, Kieran; Kumar, Prashant; Mattock, James D.; Abdul-Sada, Alaa; Pitak, Mateusz B.; Coles, Simon J.; Navarro, Oscar; Vargas, Alfredo; Kostakis, George E.
Journal of publication
Inorganic chemistry
Year of publication
2016
Journal volume
55
Journal issue
14
Pages of publication
6988 - 6994
a
12.8651 ± 0.0012 Å
b
13.5435 ± 0.0012 Å
c
14.0419 ± 0.0012 Å
α
100.536 ± 0.007°
β
106.682 ± 0.008°
γ
114.818 ± 0.008°
Cell volume
1993.6 ± 0.4 Å3
Cell temperature
100 ± 2 K
Ambient diffraction temperature
100 ± 2 K
Number of distinct elements
5
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0303
Residual factor for significantly intense reflections
0.0246
Weighted residual factors for significantly intense reflections
0.0582
Weighted residual factors for all reflections included in the refinement
0.0604
Goodness-of-fit parameter for all reflections included in the refinement
