Information card for entry 4347921

Structure parameters

• Formula: C27 H39 F3 I N3 Si3 U
• Calculated formula: C27 H39 F3 I N3 Si3 U
• SMILES: [U]1(I)(N([Si](C)(C)C)c2c(cccc2)F)(N([Si](C)(C)C)c2c(cccc2)[F]1)N([Si](C)(C)C)c1c(cccc1)F
• Title of publication: Cerium(III) and Uranium(IV) Complexes of the 2-Fluorophenyl Trimethylsilyl Amide Ligand: C-F →Ln/An Interactions that Modulate the Coordination Spheres of f-Block Elements.
• Authors of publication: Yin, Haolin; Carroll, Patrick J.; Schelter, Eric J.
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 11
• Pages of publication: 5684 - 5692
• a: 10.4057 ± 0.0009 Å
• b: 11.0327 ± 0.0008 Å
• c: 16.1084 ± 0.0013 Å
• α: 85.395 ± 0.003°
• β: 79.603 ± 0.003°
• γ: 68.152 ± 0.002°
• Cell volume: 1688.1 ± 0.2 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 ± 1 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0157
• Residual factor for significantly intense reflections: 0.0146
• Weighted residual factors for significantly intense reflections: 0.0354
• Weighted residual factors for all reflections included in the refinement: 0.0364
• Goodness-of-fit parameter for all reflections included in the refinement: 1.067
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No