Information card for entry 4348533

Structure parameters

• Formula: C69 H68 Au3 Cl9 Fe P4
• Calculated formula: C69 H68 Au3 Cl9 Fe P4
• SMILES: [c]12([cH]3[c]4([c]56[cH]1[Fe]17892346[c]2([cH]1[c]17[c]8([cH]92)[P](c2ccccc2)(c2ccccc2)[Au](Cl)[Au]([P]5(c2ccccc2)c2ccccc2)([P]1(c1ccccc1)c1ccccc1)Cl)C(C)(C)C)[P](c1ccccc1)(c1ccccc1)[Au]Cl)C(C)(C)C.C(Cl)Cl.C(Cl)Cl.C(Cl)Cl
• Title of publication: Gold(I) Complexes of Ferrocenyl Polyphosphines: Aurophilic Gold Chloride Formation and Phosphine-Concerted Shuttling of a Dinuclear [ClAu···AuCl] Fragment.
• Authors of publication: Rampazzi, Vincent; Roger, Julien; Amardeil, Régine; Penouilh, Marie-José; Richard, Philippe; Fleurat-Lessard, Paul; Hierso, Jean-Cyrille
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 21
• Pages of publication: 10907 - 10921
• a: 12.7773 ± 0.0003 Å
• b: 27.6187 ± 0.0006 Å
• c: 20.1236 ± 0.0004 Å
• α: 90°
• β: 100.41 ± 0.001°
• γ: 90°
• Cell volume: 6984.6 ± 0.3 ų
• Cell temperature: 115 K
• Ambient diffraction temperature: 115 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0278
• Residual factor for significantly intense reflections: 0.0264
• Weighted residual factors for significantly intense reflections: 0.065
• Weighted residual factors for all reflections included in the refinement: 0.0666
• Goodness-of-fit parameter for all reflections included in the refinement: 1.048
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No