Information card for entry 4349129

Structure parameters

• Formula: C93 H106 Mo4 O4 P2
• Calculated formula: C93 H106 Mo4 O4 P2
• Title of publication: Cycloaddition Reactions of the Phosphinidene-Bridged Complex [Mo₂Cp(μ-κ¹:κ¹,η⁵-PC₅H₄)(CO)₂(η⁶-HMes*)] with Diazoalkanes and Other Heterocumulenes.
• Authors of publication: Albuerne, Isabel G.; Alvarez, M. Angeles; Amor, Inmaculada; García, M Esther; García-Vivó, Daniel; Ruiz, Miguel A.
• Journal of publication: Inorganic chemistry
• Year of publication: 2016
• Journal volume: 55
• Journal issue: 20
• Pages of publication: 10680 - 10691
• a: 9.5101 ± 0.0005 Å
• b: 12.8133 ± 0.0007 Å
• c: 17.9238 ± 0.0007 Å
• α: 103.176 ± 0.004°
• β: 91.152 ± 0.004°
• γ: 109.283 ± 0.005°
• Cell volume: 1996.48 ± 0.19 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0747
• Residual factor for significantly intense reflections: 0.0529
• Weighted residual factors for significantly intense reflections: 0.1473
• Weighted residual factors for all reflections included in the refinement: 0.1579
• Goodness-of-fit parameter for all reflections included in the refinement: 1.052
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No