Information card for entry 4350120

Structure parameters

• Formula: C34 H42 Cl N4 O P2 Rh
• Calculated formula: C34 H42 Cl N4 O P2 Rh
• SMILES: [Rh]1(Cl)([P](CP(c2c(N(C)C)cccc2)c2c(N(C)C)cccc2)(c2c([N]1(C)C)cccc2)c1c(N(C)C)cccc1)C#[O]
• Title of publication: Various coordination modes of the bis(di(o-N,N-dimethylanilinyl)phosphino)methane ligand in mononuclear and binuclear complexes of group 8 and group 9 metals.
• Authors of publication: Dennett, James N. L.; Bierenstiel, Matthias; Ferguson, Michael J.; McDonald, Robert; Cowie, Martin
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 9
• Pages of publication: 3705 - 3717
• a: 15.6672 ± 0.0016 Å
• b: 14.4312 ± 0.0015 Å
• c: 15.6577 ± 0.0016 Å
• α: 90°
• β: 104.966 ± 0.002°
• γ: 90°
• Cell volume: 3420.1 ± 0.6 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0413
• Residual factor for significantly intense reflections: 0.0357
• Weighted residual factors for significantly intense reflections: 0.0958
• Weighted residual factors for all reflections included in the refinement: 0.1002
• Goodness-of-fit parameter for all reflections included in the refinement: 1.11
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No