Information card for entry 4350519

Structure parameters

• Formula: C30 H72 Cl2 Hf2 N18
• Calculated formula: C30 H72 Cl2 Hf2 N18
• SMILES: C(=N[Hf]1(Cl)(N=C(N(C)C)N(C)C)[N](=C(N(C)C)N(C)C)[Hf](Cl)([N]1=C(N(C)C)N(C)C)(N=C(N(C)C)N(C)C)N=C(N(C)C)N(C)C)(N(C)C)N(C)C
• Title of publication: Guanidinate-stabilized monomeric hafnium amide complexes as promising precursors for MOCVD of HfO2.
• Authors of publication: Milanov, Andrian; Bhakta, Raghunandan; Baunemann, Arne; Becker, Hans-Werner; Thomas, Reji; Ehrhart, Peter; Winter, Manuela; Devi, Anjana
• Journal of publication: Inorganic chemistry
• Year of publication: 2006
• Journal volume: 45
• Journal issue: 26
• Pages of publication: 11008 - 11018
• a: 10.3253 ± 0.001 Å
• b: 11.3293 ± 0.0011 Å
• c: 12.1396 ± 0.0012 Å
• α: 100.785 ± 0.008°
• β: 112.462 ± 0.009°
• γ: 110.584 ± 0.009°
• Cell volume: 1140.6 ± 0.3 ų
• Cell temperature: 104 ± 2 K
• Ambient diffraction temperature: 104 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0559
• Residual factor for significantly intense reflections: 0.0413
• Weighted residual factors for significantly intense reflections: 0.0945
• Weighted residual factors for all reflections included in the refinement: 0.0977
• Goodness-of-fit parameter for all reflections included in the refinement: 0.962
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No