Aminolactone Chiral Modifiers for Heterogeneous Asymmetric Hydrogenation: Corrected Structure of Pantoyl-Naphthylethylamine, In-Situ Hydrogenolysis, and Scanning Tunneling Microscopy Observation of Supramolecular Aminolactone/Substrate Assemblies on Pt(111)
Authors of publication
Goubert, Guillaume; Demers-Carpentier, Vincent; Loach, Richard P.; Lafleur-Lambert, Raphaél; Lemay, Jean-Christian; Boukouvalas, John; McBreen, Peter H.
Journal of publication
ACS Catalysis
Year of publication
2013
Journal volume
3
Journal issue
12
Pages of publication
2677
a
22.6541 ± 0.00016 Å
b
8.25169 ± 0.00006 Å
c
17.39574 ± 0.00012 Å
α
90°
β
107.371 ± 0.0003°
γ
90°
Cell volume
3103.55 ± 0.04 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
4
Space group number
5
Hermann-Mauguin space group symbol
C 1 2 1
Hall space group symbol
C 2y
Residual factor for all reflections
0.0303
Residual factor for significantly intense reflections
0.0301
Weighted residual factors for significantly intense reflections
0.085
Weighted residual factors for all reflections included in the refinement
0.0852
Goodness-of-fit parameter for all reflections included in the refinement
